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Ivan A. Troyan, Dmitrii V. Semenok, Alexander G. Kvashnin, A. V. Sadakov, O. A. Sobolevskiy, V. M. Pudalov, Anna Gennadievna Ivanova, Vitali B. Prakapenka, Eran Greenberg, Alexander G. Gavriliuk and 10 more
Pressure‐stabilized hydrides are a new rapidly growing class of high‐temperature superconductors, which is believed to be described within the conventional phonon‐mediated mechanism of coupling. Here, the synthesis of one of the best‐known high‐ T C superconductors—yttrium hexahydride ‐YH 6 is reported, which displays a superconducting transition at ≈224 K at 166 GPa. The extrapolated upper critical magnetic field B c2 (0) of YH 6 is surprisingly high: 116–158 T, which is 2–2.5 times larger than the calculated value. A pronounced shift of T C in yttrium deuteride YD 6 with the isotope coefficient 0.4 supports the phonon‐assisted superconductivity. Current–voltage measurements show that the critical current I C and its density J C may exceed 1.75 A and 3500 A mm −2 at 4 K, respectively, which is higher than that of the commercial superconductors, such as NbTi and YBCO. The results of superconducting density functional theory (SCDFT) and anharmonic calculations, together with anomalously high critical magnetic field, suggest notable departures of the superconducting properties from the conventional Migdal–Eliashberg and Bardeen–Cooper–Schrieffer theories, and presence of an additional mechanism of superconductivity.
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Troyan, I. A., Semenok, D. V., Kvashnin, A. G., Sadakov, A. V., Sobolevskiy, O. A., Pudalov, V. M., Ivanova, A. G., Prakapenka, V. B., Greenberg, E., Gavriliuk, A. G., Lyubutin, I. S., Struzhkin, V. V., Bergara, A., Errea, I., Bianco, R., Calandra, M., Mauri, F., Monacelli, L., Akashi, R., & Оганов, А. Р. (2021). Anomalous High‐Temperature Superconductivity in YH 6. Advanced Materials, 33(15), e2006832. https://doi.org/10.1002/adma.202006832
Troyan, Ivan A., et al. "Anomalous High‐Temperature Superconductivity in YH 6." Advanced Materials, vol. 33, no. 15, 2021, pp. e2006832, https://doi.org/10.1002/adma.202006832.
Troyan, Ivan A., Dmitrii V. Semenok, Alexander G. Kvashnin, A. V. Sadakov, O. A. Sobolevskiy, V. M. Pudalov, Anna Gennadievna Ivanova, et al. "Anomalous High‐Temperature Superconductivity in YH 6." Advanced Materials 33, no. 15 (2021): e2006832. https://doi.org/10.1002/adma.202006832.
Troyan I. A., Semenok D. V., Kvashnin A. G. [и др.] Anomalous High‐Temperature Superconductivity in YH 6 // Advanced Materials. — 2021. — Vol. 33, № 15. — P. e2006832. — URL: https://doi.org/10.1002/adma.202006832
@article{troyan2021anomalous,
title = {{Anomalous High‐Temperature Superconductivity in YH 6}},
author = {Ivan A. Troyan and Dmitrii V. Semenok and Alexander G. Kvashnin and A. V. Sadakov and O. A. Sobolevskiy and V. M. Pudalov and Anna Gennadievna Ivanova and Vitali B. Prakapenka and Eran Greenberg and Alexander G. Gavriliuk and Igor S Lyubutin and Viktor V. Struzhkin and Aitor Bergara and Ion Errea and Raffaello Bianco and Matteo Calandra and Francesco Mauri and Lorenzo Monacelli and Ryosuke Akashi and Артем Ромаевич Оганов},
journal = {Advanced Materials},
year = {2021},
volume = {33},
number = {15},
pages = {e2006832},
doi = {10.1002/adma.202006832},
url = {https://doi.org/10.1002/adma.202006832}
}TY - JOUR AU - Troyan, Ivan A. AU - Semenok, Dmitrii V. AU - Kvashnin, Alexander G. AU - Sadakov, A. V. AU - Sobolevskiy, O. A. AU - Pudalov, V. M. AU - Ivanova, Anna Gennadievna AU - Prakapenka, Vitali B. AU - Greenberg, Eran AU - Gavriliuk, Alexander G. AU - Lyubutin, Igor S AU - Struzhkin, Viktor V. AU - Bergara, Aitor AU - Errea, Ion AU - Bianco, Raffaello AU - Calandra, Matteo AU - Mauri, Francesco AU - Monacelli, Lorenzo AU - Akashi, Ryosuke AU - Оганов, Артем Ромаевич TI - Anomalous High‐Temperature Superconductivity in YH 6 JO - Advanced Materials VL - 33 IS - 15 SP - e2006832 PY - 2021 DA - 2021/03/10 DO - 10.1002/adma.202006832 UR - https://doi.org/10.1002/adma.202006832 ER -
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