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Justyna Łuczak, Malwina Kroczewska-Gnatowska, Mateusz Adam Baluk, Jakub Sowik, Paweł Mazierski, Adriana Zaleska‐Medynska
Designable morphology and predictable properties are the most challenging goals in material engineering. Features such as shape, size, porosity, agglomeration ratio significantly affect the final properties of metal-organic frameworks (MOFs) and can be regulated throughout synthesis parameters but require a deep understanding of the mechanisms of MOFs formation. Herein, we systematically summarize the effects of the individual synthesis factors, such as pH of reaction mixture, including acidic or basic character of modulators, temperature, solvents types, surfactants type and content and ionic liquids on the morphology of growing MOFs. We identified main mechanisms of MOFs' growth leading to different morphology of final particles and next systematically discuss the effect of miscellaneous parameters on MOFs morphology based on the main mechanisms related to the nucleation, growth and formation of final MOFs structure, including coordination modulation, protonation/deprotonation acting and modulation by surfactants or capping agents. The effect of microwaves and ultrasound employment during synthesis is also considered due to their affecting especially nucleation and particles growing steps during MOFs formation.
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Łuczak, J., Kroczewska-Gnatowska, M., Baluk, M. A., Sowik, J., Mazierski, P., & Zaleska‐Medynska, A. (2023). Morphology control through the synthesis of metal-organic frameworks. Advances in Colloid and Interface Science, 314, 102864. https://doi.org/10.1016/j.cis.2023.102864
Łuczak, Justyna, et al. "Morphology control through the synthesis of metal-organic frameworks." Advances in Colloid and Interface Science, vol. 314, 2023, pp. 102864, https://doi.org/10.1016/j.cis.2023.102864.
Łuczak, Justyna, Malwina Kroczewska-Gnatowska, Mateusz Adam Baluk, Jakub Sowik, Paweł Mazierski, and Adriana Zaleska‐Medynska. "Morphology control through the synthesis of metal-organic frameworks." Advances in Colloid and Interface Science 314 (2023): 102864. https://doi.org/10.1016/j.cis.2023.102864.
Łuczak J., Kroczewska-Gnatowska M., Baluk M. A. [и др.] Morphology control through the synthesis of metal-organic frameworks // Advances in Colloid and Interface Science. — 2023. — Vol. 314. — P. 102864. — URL: https://doi.org/10.1016/j.cis.2023.102864
@article{uczak2023morphology,
title = {{Morphology control through the synthesis of metal-organic frameworks}},
author = {Justyna Łuczak and Malwina Kroczewska-Gnatowska and Mateusz Adam Baluk and Jakub Sowik and Paweł Mazierski and Adriana Zaleska‐Medynska},
journal = {Advances in Colloid and Interface Science},
year = {2023},
volume = {314},
pages = {102864},
doi = {10.1016/j.cis.2023.102864},
url = {https://doi.org/10.1016/j.cis.2023.102864}
}TY - JOUR AU - Łuczak, Justyna AU - Kroczewska-Gnatowska, Malwina AU - Baluk, Mateusz Adam AU - Sowik, Jakub AU - Mazierski, Paweł AU - Zaleska‐Medynska, Adriana TI - Morphology control through the synthesis of metal-organic frameworks JO - Advances in Colloid and Interface Science VL - 314 SP - 102864 PY - 2023 DA - 2023/02/26 DO - 10.1016/j.cis.2023.102864 UR - https://doi.org/10.1016/j.cis.2023.102864 ER -
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