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Jun Kee Cheng, Shao‐Hua Xiang, Shaoyu Li, Ye Liu, Bin Tan
Atropisomerism is a stereochemical behavior portrayed by three-dimensional molecules that bear rotationally restricted σ bond. Akin to the well-represented point-chiral molecules, atropisomerically chiral compounds are finding increasing utilities in many disciplines where molecular asymmetry is influential. This provides steady demand on atroposelective synthesis, where numerous synthetic pursuits have been rewarded with conceptually novel and streamlined methods while expanding the structural diversity of atropisomers. This review summarizes key achievements in stereoselective preparation of biaryl, heterobiaryl, and nonbiaryl atropisomers documented between 2015 and 2020. Emphasis is placed on the synthetic strategies for each structural class, while examples are cited to illustrate the potential applications of the accessed atropochiral targets.
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Cheng, J. K., Xiang, S., Li, S., Liu, Y., & Tan, B. (2021). Recent Advances in Catalytic Asymmetric Construction of Atropisomers. Chemical Reviews, 121(8), 4805–4902. https://doi.org/10.1021/acs.chemrev.0c01306
Cheng, Jun Kee, et al. "Recent Advances in Catalytic Asymmetric Construction of Atropisomers." Chemical Reviews, vol. 121, no. 8, 2021, pp. 4805–4902, https://doi.org/10.1021/acs.chemrev.0c01306.
Cheng, Jun Kee, Shao‐Hua Xiang, Shaoyu Li, Ye Liu, and Bin Tan. "Recent Advances in Catalytic Asymmetric Construction of Atropisomers." Chemical Reviews 121, no. 8 (2021): 4805–4902. https://doi.org/10.1021/acs.chemrev.0c01306.
Cheng J. K., Xiang S., Li S. [и др.] Recent Advances in Catalytic Asymmetric Construction of Atropisomers // Chemical Reviews. — 2021. — Vol. 121, № 8. — P. 4805–4902. — URL: https://doi.org/10.1021/acs.chemrev.0c01306
@article{cheng2021recent,
title = {{Recent Advances in Catalytic Asymmetric Construction of Atropisomers}},
author = {Jun Kee Cheng and Shao‐Hua Xiang and Shaoyu Li and Ye Liu and Bin Tan},
journal = {Chemical Reviews},
year = {2021},
volume = {121},
number = {8},
pages = {4805--4902},
doi = {10.1021/acs.chemrev.0c01306},
url = {https://doi.org/10.1021/acs.chemrev.0c01306}
}TY - JOUR AU - Cheng, Jun Kee AU - Xiang, Shao‐Hua AU - Li, Shaoyu AU - Liu, Ye AU - Tan, Bin TI - Recent Advances in Catalytic Asymmetric Construction of Atropisomers JO - Chemical Reviews VL - 121 IS - 8 SP - 4805 EP - 4902 PY - 2021 DA - 2021/03/27 DO - 10.1021/acs.chemrev.0c01306 UR - https://doi.org/10.1021/acs.chemrev.0c01306 ER -
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