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Soumya Kumar Sinha, Srimanta Guin, Sudip Maiti, Jyoti Prasad Biswas, Sandip Porey, Debabrata Maiti
Transition-metal-catalyzed C-H activation has developed a contemporary approach to the omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted to take the help of this methodology to plan their synthetic discourses. This paradigm shift has helped in the development of industrial units as well, making the synthesis of natural products and pharmaceutical drugs step-economical. In the vast zone of C-H bond activation, the functionalization of proximal C-H bonds has gained utmost popularity. Unlike the activation of proximal C-H bonds, the distal C-H functionalization is more strenuous and requires distinctly specialized techniques. In this review, we have compiled various methods adopted to functionalize distal C-H bonds, mechanistic insights within each of these procedures, and the scope of the methodology. With this review, we give a complete overview of the expeditious progress the distal C-H activation has made in the field of synthetic organic chemistry while also highlighting its pitfalls, thus leaving the field open for further synthetic modifications.
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Sinha, S. K., Guin, S., Maiti, S., Biswas, J. P., Porey, S., & Maiti, D. (2021). Toolbox for Distal C–H Bond Functionalizations in Organic Molecules. Chemical Reviews, 122(6), 5682–5841. https://doi.org/10.1021/acs.chemrev.1c00220
Sinha, Soumya Kumar, et al. "Toolbox for Distal C–H Bond Functionalizations in Organic Molecules." Chemical Reviews, vol. 122, no. 6, 2021, pp. 5682–5841, https://doi.org/10.1021/acs.chemrev.1c00220.
Sinha, Soumya Kumar, Srimanta Guin, Sudip Maiti, Jyoti Prasad Biswas, Sandip Porey, and Debabrata Maiti. "Toolbox for Distal C–H Bond Functionalizations in Organic Molecules." Chemical Reviews 122, no. 6 (2021): 5682–5841. https://doi.org/10.1021/acs.chemrev.1c00220.
Sinha S. K., Guin S., Maiti S. [и др.] Toolbox for Distal C–H Bond Functionalizations in Organic Molecules // Chemical Reviews. — 2021. — Vol. 122, № 6. — P. 5682–5841. — URL: https://doi.org/10.1021/acs.chemrev.1c00220
@article{sinha2021toolbox,
title = {{Toolbox for Distal C–H Bond Functionalizations in Organic Molecules}},
author = {Soumya Kumar Sinha and Srimanta Guin and Sudip Maiti and Jyoti Prasad Biswas and Sandip Porey and Debabrata Maiti},
journal = {Chemical Reviews},
year = {2021},
volume = {122},
number = {6},
pages = {5682--5841},
doi = {10.1021/acs.chemrev.1c00220},
url = {https://doi.org/10.1021/acs.chemrev.1c00220}
}TY - JOUR AU - Sinha, Soumya Kumar AU - Guin, Srimanta AU - Maiti, Sudip AU - Biswas, Jyoti Prasad AU - Porey, Sandip AU - Maiti, Debabrata TI - Toolbox for Distal C–H Bond Functionalizations in Organic Molecules JO - Chemical Reviews VL - 122 IS - 6 SP - 5682 EP - 5841 PY - 2021 DA - 2021/10/18 DO - 10.1021/acs.chemrev.1c00220 UR - https://doi.org/10.1021/acs.chemrev.1c00220 ER -
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