One connector, four scholarly indexes, real DOIs and legal free PDFs. Works in Claude and ChatGPT.
Paste it into Claude or ChatGPT as a custom connector. 3-day free trial.
Johannes J. Großkopf, Thilo Kratz, Thomas Rigotti, Thorsten Bach
For molecules with a singlet ground state, the population of triplet states is mainly possible (a) by direct excitation and subsequent intersystem crossing or (b) by energy transfer from an appropriate sensitizer. The latter scenario enables a catalytic photochemical reaction in which the sensitizer adopts the role of a catalyst undergoing several cycles of photon absorption and subsequent energy transfer to the substrate. If the product molecule of a triplet-sensitized process is chiral, this process can proceed enantioselectively upon judicious choice of a chiral triplet sensitizer. An enantioselective reaction can also occur in a dual catalytic approach in which, apart from an achiral sensitizer, a second chiral catalyst activates the substrate toward sensitization. Although the idea of enantioselective photochemical reactions via triplet intermediates has been pursued for more than 50 years, notable selectivities exceeding 90% enantiomeric excess ( ee ) have only been realized in the past decade. This review attempts to provide a comprehensive survey on the various photochemical reactions which were rendered enantioselective by triplet sensitization.
Formatted from the source metadata, not typed by hand. For a whole reference list, use the citation generator or ask your assistant through Find Research.
Großkopf, J. J., Kratz, T., Rigotti, T., & Bach, T. (2021). Enantioselective Photochemical Reactions Enabled by Triplet Energy Transfer. Chemical Reviews, 122(2), 1626–1653. https://doi.org/10.1021/acs.chemrev.1c00272
Großkopf, Johannes J., et al. "Enantioselective Photochemical Reactions Enabled by Triplet Energy Transfer." Chemical Reviews, vol. 122, no. 2, 2021, pp. 1626–1653, https://doi.org/10.1021/acs.chemrev.1c00272.
Großkopf, Johannes J., Thilo Kratz, Thomas Rigotti, and Thorsten Bach. "Enantioselective Photochemical Reactions Enabled by Triplet Energy Transfer." Chemical Reviews 122, no. 2 (2021): 1626–1653. https://doi.org/10.1021/acs.chemrev.1c00272.
Großkopf J. J., Kratz T., Rigotti T. [и др.] Enantioselective Photochemical Reactions Enabled by Triplet Energy Transfer // Chemical Reviews. — 2021. — Vol. 122, № 2. — P. 1626–1653. — URL: https://doi.org/10.1021/acs.chemrev.1c00272
@article{grokopf2021enantioselective,
title = {{Enantioselective Photochemical Reactions Enabled by Triplet Energy Transfer}},
author = {Johannes J. Großkopf and Thilo Kratz and Thomas Rigotti and Thorsten Bach},
journal = {Chemical Reviews},
year = {2021},
volume = {122},
number = {2},
pages = {1626--1653},
doi = {10.1021/acs.chemrev.1c00272},
url = {https://doi.org/10.1021/acs.chemrev.1c00272}
}TY - JOUR AU - Großkopf, Johannes J. AU - Kratz, Thilo AU - Rigotti, Thomas AU - Bach, Thorsten TI - Enantioselective Photochemical Reactions Enabled by Triplet Energy Transfer JO - Chemical Reviews VL - 122 IS - 2 SP - 1626 EP - 1653 PY - 2021 DA - 2021/07/06 DO - 10.1021/acs.chemrev.1c00272 UR - https://doi.org/10.1021/acs.chemrev.1c00272 ER -
Add Find Research to Claude or ChatGPT and ask in plain language. The assistant reads this record, finds the papers around it and cites only what it actually found:
Setup takes about a minute: add the connector, then start the free trial.
Record from OpenAlex. Find Research links only to legal copies.