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Eduardo Pérez‐Botella, Susana Valencia, Fernando Rey
Zeolites have been widely used as catalysts, ion exchangers, and adsorbents since their industrial breakthrough in the 1950s and continue to be state-of the-art adsorbents in many separation processes. Furthermore, their properties make them materials of choice for developing and emerging separation applications. The aim of this review is to put into context the relevance of zeolites and their use and prospects in adsorption technology. It has been divided into three different sections, i.e., zeolites, adsorption on nanoporous materials, and chemical separations by zeolites. In the first section, zeolites are explained in terms of their structure, composition, preparation, and properties, and a brief review of their applications is given. In the second section, the fundamentals of adsorption science are presented, with special attention to its industrial application and our case of interest, which is adsorption on zeolites. Finally, the state-of-the-art relevant separations related to chemical and energy production, in which zeolites have a practical or potential applicability, are presented. The replacement of some of the current separation methods by optimized adsorption processes using zeolites could mean an improvement in terms of sustainability and energy savings. Different separation mechanisms and the underlying adsorption properties that make zeolites interesting for these applications are discussed.
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Pérez‐Botella, E., Valencia, S., & Rey, F. (2022). Zeolites in Adsorption Processes: State of the Art and Future Prospects. Chemical Reviews, 122(24), 17647–17695. https://doi.org/10.1021/acs.chemrev.2c00140
Pérez‐Botella, Eduardo, et al. "Zeolites in Adsorption Processes: State of the Art and Future Prospects." Chemical Reviews, vol. 122, no. 24, 2022, pp. 17647–17695, https://doi.org/10.1021/acs.chemrev.2c00140.
Pérez‐Botella, Eduardo, Susana Valencia, and Fernando Rey. "Zeolites in Adsorption Processes: State of the Art and Future Prospects." Chemical Reviews 122, no. 24 (2022): 17647–17695. https://doi.org/10.1021/acs.chemrev.2c00140.
Pérez‐Botella E., Valencia S., Rey F. Zeolites in Adsorption Processes: State of the Art and Future Prospects // Chemical Reviews. — 2022. — Vol. 122, № 24. — P. 17647–17695. — URL: https://doi.org/10.1021/acs.chemrev.2c00140
@article{perezbotella2022zeolites,
title = {{Zeolites in Adsorption Processes: State of the Art and Future Prospects}},
author = {Eduardo Pérez‐Botella and Susana Valencia and Fernando Rey},
journal = {Chemical Reviews},
year = {2022},
volume = {122},
number = {24},
pages = {17647--17695},
doi = {10.1021/acs.chemrev.2c00140},
url = {https://doi.org/10.1021/acs.chemrev.2c00140}
}TY - JOUR AU - Pérez‐Botella, Eduardo AU - Valencia, Susana AU - Rey, Fernando TI - Zeolites in Adsorption Processes: State of the Art and Future Prospects JO - Chemical Reviews VL - 122 IS - 24 SP - 17647 EP - 17695 PY - 2022 DA - 2022/10/19 DO - 10.1021/acs.chemrev.2c00140 UR - https://doi.org/10.1021/acs.chemrev.2c00140 ER -
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