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Xueqin Li, Kai Chen, Ruili Guo, Zhong Wei
Metal–organic frameworks (MOFs) and ionic liquids (ILs) represent promising materials for adsorption separation. ILs incorporated into MOF materials (denoted as IL/MOF composites) have been developed, and IL/MOF composites combine the advantages of MOFs and ILs to achieve enhanced performance in the adsorption-based separation of fluid mixtures. The designed different ILs are introduced into the various MOFs to tailor their functional properties, which affect the optimal adsorptive separation performance. In this Perspective, the rational fabrication of IL/MOF composites is presented, and their functional properties are demonstrated. This paper provides a critical overview of an emergent class of materials termed IL/MOF composites as well as the recent advances in the applications of IL/MOF composites as adsorbents or membranes in fluid separation. Furthermore, the applications of IL/MOF in adsorptive gas separations (CO 2 capture from flue gas, natural gas purification, separation of acetylene and ethylene, indoor pollutants removal) and liquid separations (separation of bioactive components, organic-contaminant removal, adsorptive desulfurization, radionuclide removal) are discussed. Finally, the existing challenges of IL/MOF are highlighted, and an appropriate design strategy direction for the effective exploration of new IL/MOF adsorptive materials is proposed.
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Li, X., Chen, K., Guo, R., & Wei, Z. (2023). Ionic Liquids Functionalized MOFs for Adsorption. Chemical Reviews, 123(16), 10432–10467. https://doi.org/10.1021/acs.chemrev.3c00248
Li, Xueqin, et al. "Ionic Liquids Functionalized MOFs for Adsorption." Chemical Reviews, vol. 123, no. 16, 2023, pp. 10432–10467, https://doi.org/10.1021/acs.chemrev.3c00248.
Li, Xueqin, Kai Chen, Ruili Guo, and Zhong Wei. "Ionic Liquids Functionalized MOFs for Adsorption." Chemical Reviews 123, no. 16 (2023): 10432–10467. https://doi.org/10.1021/acs.chemrev.3c00248.
Li X., Chen K., Guo R. [и др.] Ionic Liquids Functionalized MOFs for Adsorption // Chemical Reviews. — 2023. — Vol. 123, № 16. — P. 10432–10467. — URL: https://doi.org/10.1021/acs.chemrev.3c00248
@article{li2023ionic,
title = {{Ionic Liquids Functionalized MOFs for Adsorption}},
author = {Xueqin Li and Kai Chen and Ruili Guo and Zhong Wei},
journal = {Chemical Reviews},
year = {2023},
volume = {123},
number = {16},
pages = {10432--10467},
doi = {10.1021/acs.chemrev.3c00248},
url = {https://doi.org/10.1021/acs.chemrev.3c00248}
}TY - JOUR AU - Li, Xueqin AU - Chen, Kai AU - Guo, Ruili AU - Wei, Zhong TI - Ionic Liquids Functionalized MOFs for Adsorption JO - Chemical Reviews VL - 123 IS - 16 SP - 10432 EP - 10467 PY - 2023 DA - 2023/07/14 DO - 10.1021/acs.chemrev.3c00248 UR - https://doi.org/10.1021/acs.chemrev.3c00248 ER -
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