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Shams Kalam, Sidqi A. Abu-Khamsin, Muhammad Shahzad Kamal, Shirish L. Patil
The need to minimize surfactant adsorption on rock surfaces has been a challenge for surfactant-based, chemical-enhanced oil recovery (cEOR) techniques. Modeling of adsorption experimental data is very useful in estimating the extent of adsorption and, hence, optimizing the process. This paper presents a mini-review of surfactant adsorption isotherms, focusing on theories of adsorption and the most frequently used adsorption isotherm models. Two-step and four-region adsorption theories are well-known, with the former representing adsorption in two steps, while the latter distinguishes four regions in the adsorption isotherm. Langmuir and Freundlich are two-parameter adsorption isotherms that are widely used in cEOR studies. The Langmuir isotherm is applied to monolayer adsorption on homogeneous sites, whereas the Freundlich isotherm suites are applied to multilayer adsorption on heterogeneous sites. Some more complex adsorption isotherms are also discussed in this paper, such as Redlich-Peterson and Sips isotherms, both involve three parameters. This paper will help select and apply a suitable adsorption isotherm to experimental data.
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Kalam, S., Abu-Khamsin, S. A., Kamal, M. S., & Patil, S. L. (2021). Surfactant Adsorption Isotherms: A Review. ACS Omega, 6(48), 32342–32348. https://doi.org/10.1021/acsomega.1c04661
Kalam, Shams, et al. "Surfactant Adsorption Isotherms: A Review." ACS Omega, vol. 6, no. 48, 2021, pp. 32342–32348, https://doi.org/10.1021/acsomega.1c04661.
Kalam, Shams, Sidqi A. Abu-Khamsin, Muhammad Shahzad Kamal, and Shirish L. Patil. "Surfactant Adsorption Isotherms: A Review." ACS Omega 6, no. 48 (2021): 32342–32348. https://doi.org/10.1021/acsomega.1c04661.
Kalam S., Abu-Khamsin S. A., Kamal M. S. [и др.] Surfactant Adsorption Isotherms: A Review // ACS Omega. — 2021. — Vol. 6, № 48. — P. 32342–32348. — URL: https://doi.org/10.1021/acsomega.1c04661
@article{kalam2021surfactant,
title = {{Surfactant Adsorption Isotherms: A Review}},
author = {Shams Kalam and Sidqi A. Abu-Khamsin and Muhammad Shahzad Kamal and Shirish L. Patil},
journal = {ACS Omega},
year = {2021},
volume = {6},
number = {48},
pages = {32342--32348},
doi = {10.1021/acsomega.1c04661},
url = {https://doi.org/10.1021/acsomega.1c04661}
}TY - JOUR AU - Kalam, Shams AU - Abu-Khamsin, Sidqi A. AU - Kamal, Muhammad Shahzad AU - Patil, Shirish L. TI - Surfactant Adsorption Isotherms: A Review JO - ACS Omega VL - 6 IS - 48 SP - 32342 EP - 32348 PY - 2021 DA - 2021/11/24 DO - 10.1021/acsomega.1c04661 UR - https://doi.org/10.1021/acsomega.1c04661 ER -
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