One connector, four scholarly indexes, real DOIs and legal free PDFs. Works in Claude and ChatGPT.
Paste it into Claude or ChatGPT as a custom connector. 3-day free trial.
Robin Tyburski, Tianfei Liu, Starla D. Glover, Leif Hammarström
Proton-coupled electron transfer (PCET) reactions are fundamental to energy transformation reactions in natural and artificial systems and are increasingly recognized in areas such as catalysis and synthetic chemistry. The interdependence of proton and electron transfer brings a mechanistic richness of reactivity, including various sequential and concerted mechanisms. Delineating between different PCET mechanisms and understanding why a particular mechanism dominates are crucial for the design and optimization of reactions that use PCET. This Perspective provides practical guidelines for how to discern between sequential and concerted mechanisms based on interpretations of thermodynamic data with temperature-, pressure-, and isotope-dependent kinetics. We present new PCET-zone diagrams that show how a mechanism can switch or even be eliminated by varying the thermodynamic (ΔGPT° and ΔGET°) and coupling strengths for a PCET system. We discuss the appropriateness of asynchronous concerted PCET to rationalize observations in organic reactions, and the distinction between hydrogen atom transfer and other concerted PCET reactions. Contemporary issues and future prospects in PCET research are discussed.
Formatted from the source metadata, not typed by hand. For a whole reference list, use the citation generator or ask your assistant through Find Research.
Tyburski, R., Liu, T., Glover, S. D., & Hammarström, L. (2021). Proton-Coupled Electron Transfer Guidelines, Fair and Square. Journal of the American Chemical Society, 143(2), 560–576. https://doi.org/10.1021/jacs.0c09106
Tyburski, Robin, et al. "Proton-Coupled Electron Transfer Guidelines, Fair and Square." Journal of the American Chemical Society, vol. 143, no. 2, 2021, pp. 560–576, https://doi.org/10.1021/jacs.0c09106.
Tyburski, Robin, Tianfei Liu, Starla D. Glover, and Leif Hammarström. "Proton-Coupled Electron Transfer Guidelines, Fair and Square." Journal of the American Chemical Society 143, no. 2 (2021): 560–576. https://doi.org/10.1021/jacs.0c09106.
Tyburski R., Liu T., Glover S. D. [и др.] Proton-Coupled Electron Transfer Guidelines, Fair and Square // Journal of the American Chemical Society. — 2021. — Vol. 143, № 2. — P. 560–576. — URL: https://doi.org/10.1021/jacs.0c09106
@article{tyburski2021protoncoupled,
title = {{Proton-Coupled Electron Transfer Guidelines, Fair and Square}},
author = {Robin Tyburski and Tianfei Liu and Starla D. Glover and Leif Hammarström},
journal = {Journal of the American Chemical Society},
year = {2021},
volume = {143},
number = {2},
pages = {560--576},
doi = {10.1021/jacs.0c09106},
url = {https://doi.org/10.1021/jacs.0c09106}
}TY - JOUR AU - Tyburski, Robin AU - Liu, Tianfei AU - Glover, Starla D. AU - Hammarström, Leif TI - Proton-Coupled Electron Transfer Guidelines, Fair and Square JO - Journal of the American Chemical Society VL - 143 IS - 2 SP - 560 EP - 576 PY - 2021 DA - 2021/01/06 DO - 10.1021/jacs.0c09106 UR - https://doi.org/10.1021/jacs.0c09106 ER -
Add Find Research to Claude or ChatGPT and ask in plain language. The assistant reads this record, finds the papers around it and cites only what it actually found:
Setup takes about a minute: add the connector, then start the free trial.
Record from OpenAlex; open-access location from Unpaywall and the indexes. Find Research links only to legal copies.