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Zhenyu Wu, Mohammadreza Karamad, Xue Yong, Qizheng Huang, David A. Cullen, Peng Zhu, Chuan Xia, Qunfeng Xiao, Mohsen Shakouri, Feng-Yang Chen and 9 more
Electrochemically converting nitrate, a widespread water pollutant, back to valuable ammonia is a green and delocalized route for ammonia synthesis, and can be an appealing and supplementary alternative to the Haber-Bosch process. However, as there are other nitrate reduction pathways present, selectively guiding the reaction pathway towards ammonia is currently challenged by the lack of efficient catalysts. Here we report a selective and active nitrate reduction to ammonia on Fe single atom catalyst, with a maximal ammonia Faradaic efficiency of ~ 75% and a yield rate of up to ~ 20,000 μg h −1 mg cat. −1 (0.46 mmol h −1 cm −2 ). Our Fe single atom catalyst can effectively prevent the N-N coupling step required for N 2 due to the lack of neighboring metal sites, promoting ammonia product selectivity. Density functional theory calculations reveal the reaction mechanisms and the potential limiting steps for nitrate reduction on atomically dispersed Fe sites.
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Wu, Z., Karamad, M., Yong, X., Huang, Q., Cullen, D. A., Zhu, P., Xia, C., Xiao, Q., Shakouri, M., Chen, F.-Y., Kim, J. Y., Yang, X., Heck, K. N., Hu, Y., Wong, M. S., Li, Q., Gates, I. D., Siahrostami, S., & Wang, H. (2021). Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst. Nature Communications, 12(1), 2870. https://doi.org/10.1038/s41467-021-23115-x
Wu, Zhenyu, et al. "Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst." Nature Communications, vol. 12, no. 1, 2021, pp. 2870, https://doi.org/10.1038/s41467-021-23115-x.
Wu, Zhenyu, Mohammadreza Karamad, Xue Yong, Qizheng Huang, David A. Cullen, Peng Zhu, Chuan Xia, et al. "Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst." Nature Communications 12, no. 1 (2021): 2870. https://doi.org/10.1038/s41467-021-23115-x.
Wu Z., Karamad M., Yong X. [и др.] Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst // Nature Communications. — 2021. — Vol. 12, № 1. — P. 2870. — URL: https://doi.org/10.1038/s41467-021-23115-x
@article{wu2021electrochemical,
title = {{Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst}},
author = {Zhenyu Wu and Mohammadreza Karamad and Xue Yong and Qizheng Huang and David A. Cullen and Peng Zhu and Chuan Xia and Qunfeng Xiao and Mohsen Shakouri and Feng-Yang Chen and Jung Yoon Kim and Xia Yang and Kimberly N. Heck and Yongfeng Hu and Michael S. Wong and Qilin Li and Ian Donald Gates and Samira Siahrostami and Haotian Wang},
journal = {Nature Communications},
year = {2021},
volume = {12},
number = {1},
pages = {2870},
doi = {10.1038/s41467-021-23115-x},
url = {https://doi.org/10.1038/s41467-021-23115-x}
}TY - JOUR AU - Wu, Zhenyu AU - Karamad, Mohammadreza AU - Yong, Xue AU - Huang, Qizheng AU - Cullen, David A. AU - Zhu, Peng AU - Xia, Chuan AU - Xiao, Qunfeng AU - Shakouri, Mohsen AU - Chen, Feng-Yang AU - Kim, Jung Yoon AU - Yang, Xia AU - Heck, Kimberly N. AU - Hu, Yongfeng AU - Wong, Michael S. AU - Li, Qilin AU - Gates, Ian Donald AU - Siahrostami, Samira AU - Wang, Haotian TI - Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst JO - Nature Communications VL - 12 IS - 1 SP - 2870 PY - 2021 DA - 2021/05/17 DO - 10.1038/s41467-021-23115-x UR - https://doi.org/10.1038/s41467-021-23115-x ER -
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