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Eamonn Murphy, Yuanchao Liu, Ivana Matanović, Martina Rüscher, Ying Lei Huang, Alvin Ly, Shengyuan Guo, Wenjie Zang, Xingxu Yan, Andrea Martini and 6 more
Electrocatalytic reduction of waste nitrates (NO 3 − ) enables the synthesis of ammonia (NH 3 ) in a carbon neutral and decentralized manner. Atomically dispersed metal-nitrogen-carbon (M-N-C) catalysts demonstrate a high catalytic activity and uniquely favor mono-nitrogen products. However, the reaction fundamentals remain largely underexplored. Herein, we report a set of 14; 3 d -, 4 d -, 5 d - and f -block M-N-C catalysts. The selectivity and activity of NO 3 − reduction to NH 3 in neutral media, with a specific focus on deciphering the role of the NO 2 − intermediate in the reaction cascade, reveals strong correlations (R=0.9) between the NO 2 − reduction activity and NO 3 − reduction selectivity for NH 3 . Moreover, theoretical computations reveal the associative/dissociative adsorption pathways for NO 2 − evolution, over the normal M-N 4 sites and their oxo-form (O-M-N 4 ) for oxyphilic metals. This work provides a platform for designing multi-element NO 3 RR cascades with single-atom sites or their hybridization with extended catalytic surfaces.
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Murphy, E., Liu, Y., Matanović, I., Rüscher, M., Huang, Y. L., Ly, A., Guo, S., Zang, W., Yan, X., Martini, A., Timoshenko, J., Cuenya, B. R., Zenyuk, I. V., Pan, X. Q., Spoerke, E. D., & Atanassov, P. B. (2023). Elucidating electrochemical nitrate and nitrite reduction over atomically-dispersed transition metal sites. Nature Communications, 14(1), 4554. https://doi.org/10.1038/s41467-023-40174-4
Murphy, Eamonn, et al. "Elucidating electrochemical nitrate and nitrite reduction over atomically-dispersed transition metal sites." Nature Communications, vol. 14, no. 1, 2023, pp. 4554, https://doi.org/10.1038/s41467-023-40174-4.
Murphy, Eamonn, Yuanchao Liu, Ivana Matanović, Martina Rüscher, Ying Lei Huang, Alvin Ly, Shengyuan Guo, et al. "Elucidating electrochemical nitrate and nitrite reduction over atomically-dispersed transition metal sites." Nature Communications 14, no. 1 (2023): 4554. https://doi.org/10.1038/s41467-023-40174-4.
Murphy E., Liu Y., Matanović I. [и др.] Elucidating electrochemical nitrate and nitrite reduction over atomically-dispersed transition metal sites // Nature Communications. — 2023. — Vol. 14, № 1. — P. 4554. — URL: https://doi.org/10.1038/s41467-023-40174-4
@article{murphy2023elucidating,
title = {{Elucidating electrochemical nitrate and nitrite reduction over atomically-dispersed transition metal sites}},
author = {Eamonn Murphy and Yuanchao Liu and Ivana Matanović and Martina Rüscher and Ying Lei Huang and Alvin Ly and Shengyuan Guo and Wenjie Zang and Xingxu Yan and Andrea Martini and Janis Timoshenko and Beatriz Roldán Cuenya and Iryna V. Zenyuk and Xiaoqing Q. Pan and Erik David Spoerke and Plamen B. Atanassov},
journal = {Nature Communications},
year = {2023},
volume = {14},
number = {1},
pages = {4554},
doi = {10.1038/s41467-023-40174-4},
url = {https://doi.org/10.1038/s41467-023-40174-4}
}TY - JOUR AU - Murphy, Eamonn AU - Liu, Yuanchao AU - Matanović, Ivana AU - Rüscher, Martina AU - Huang, Ying Lei AU - Ly, Alvin AU - Guo, Shengyuan AU - Zang, Wenjie AU - Yan, Xingxu AU - Martini, Andrea AU - Timoshenko, Janis AU - Cuenya, Beatriz Roldán AU - Zenyuk, Iryna V. AU - Pan, Xiaoqing Q. AU - Spoerke, Erik David AU - Atanassov, Plamen B. TI - Elucidating electrochemical nitrate and nitrite reduction over atomically-dispersed transition metal sites JO - Nature Communications VL - 14 IS - 1 SP - 4554 PY - 2023 DA - 2023/07/28 DO - 10.1038/s41467-023-40174-4 UR - https://doi.org/10.1038/s41467-023-40174-4 ER -
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