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José A. Carmona, Carlos Rodríguez-Franco, Rosario Fernández, Valentı́n Hornillos, José M. Lassaletta
This tutorial review provides a systematic overview of the available methodologies for the atroposelective transformation of (heterobiaryl)biaryl precursors toward the synthesis of enantiomerically enriched products and the conceptual aspects associated to each type of transformation. Depending on the presence or absence of symmetry in the starting material and the participation of racemization or dynamization events along the process, several strategies have been developed, including desymmetrization, classical kinetic resolution (KR), dynamic kinetic resolution (DKR) and dynamic kinetic asymmetric transformation (DYKAT). Seminal contributions and a handful of selected examples are discussed to illustrate the potential of these synthetic tools.
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Carmona, J. A., Rodríguez-Franco, C., Fernández, R., Hornillos, V., & Lassaletta, J. M. (2021). Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies. Chemical Society Reviews, 50(5), 2968–2983. https://doi.org/10.1039/d0cs00870b
Carmona, José A., et al. "Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies." Chemical Society Reviews, vol. 50, no. 5, 2021, pp. 2968–2983, https://doi.org/10.1039/d0cs00870b.
Carmona, José A., Carlos Rodríguez-Franco, Rosario Fernández, Valentı́n Hornillos, and José M. Lassaletta. "Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies." Chemical Society Reviews 50, no. 5 (2021): 2968–2983. https://doi.org/10.1039/d0cs00870b.
Carmona J. A., Rodríguez-Franco C., Fernández R. [и др.] Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies // Chemical Society Reviews. — 2021. — Vol. 50, № 5. — P. 2968–2983. — URL: https://doi.org/10.1039/d0cs00870b
@article{carmona2021atroposelective,
title = {{Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies}},
author = {José A. Carmona and Carlos Rodríguez-Franco and Rosario Fernández and Valentı́n Hornillos and José M. Lassaletta},
journal = {Chemical Society Reviews},
year = {2021},
volume = {50},
number = {5},
pages = {2968--2983},
doi = {10.1039/d0cs00870b},
url = {https://doi.org/10.1039/d0cs00870b}
}TY - JOUR AU - Carmona, José A. AU - Rodríguez-Franco, Carlos AU - Fernández, Rosario AU - Hornillos, Valentı́n AU - Lassaletta, José M. TI - Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies JO - Chemical Society Reviews VL - 50 IS - 5 SP - 2968 EP - 2983 PY - 2021 DA - 2021/01/01 DO - 10.1039/d0cs00870b UR - https://doi.org/10.1039/d0cs00870b ER -
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