- Published
- 2021-01-01
- Venue
- Chemical Society Reviews, vol. 50, no. 22, pp. 12656-12678
- Cited by
- 712
- Open access
- No free copy found
- DOI
- 10.1039/d1cs00239b
- PubMed
- 34633008
Abstract
The twisted intramolecular charge transfer (TICT) mechanism has guided the development of numerous bright and sensitive fluorophores. This review briefly overviews the history of establishing the TICT mechanism, and systematically summarizes the molecular design strategies in modulating the TICT tendency of various organic fluorophores towards different applications, along with key milestone studies and representative examples. Additionally, we also succinctly review the twisted intramolecular charge shuttle (TICS) and twists during photoinduced electron transfer (PET), and compare their similarities and differences with TICT, with emphasis on understanding the structure-property relationships between the twisted geometries and how they can directly affect the fluorescence of the molecules. Such structure-property relationships presented herein will greatly aid the rational development of fluorophores that involve molecular twisting in the excited state.
Cite this paper
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- APA 7
Wang, C., Chi, W., Qiao, Q., Tan, D., Xu, Z., & Liu, X. (2021). Twisted intramolecular charge transfer (TICT) and twists beyond TICT: from mechanisms to rational designs of bright and sensitive fluorophores. Chemical Society Reviews, 50(22), 12656–12678. https://doi.org/10.1039/d1cs00239b
- MLA 9
Wang, Chao, et al. "Twisted intramolecular charge transfer (TICT) and twists beyond TICT: from mechanisms to rational designs of bright and sensitive fluorophores." Chemical Society Reviews, vol. 50, no. 22, 2021, pp. 12656–12678, https://doi.org/10.1039/d1cs00239b.
- Chicago
Wang, Chao, Weijie Chi, Qinglong Qiao, Davin Tan, Zhaochao Xu, and Xiaogang Liu. "Twisted intramolecular charge transfer (TICT) and twists beyond TICT: from mechanisms to rational designs of bright and sensitive fluorophores." Chemical Society Reviews 50, no. 22 (2021): 12656–12678. https://doi.org/10.1039/d1cs00239b.
- GOST
Wang C., Chi W., Qiao Q. [и др.] Twisted intramolecular charge transfer (TICT) and twists beyond TICT: from mechanisms to rational designs of bright and sensitive fluorophores // Chemical Society Reviews. — 2021. — Vol. 50, № 22. — P. 12656–12678. — URL: https://doi.org/10.1039/d1cs00239b
- BibTeX
@article{wang2021twisted, title = {{Twisted intramolecular charge transfer (TICT) and twists beyond TICT: from mechanisms to rational designs of bright and sensitive fluorophores}}, author = {Chao Wang and Weijie Chi and Qinglong Qiao and Davin Tan and Zhaochao Xu and Xiaogang Liu}, journal = {Chemical Society Reviews}, year = {2021}, volume = {50}, number = {22}, pages = {12656--12678}, doi = {10.1039/d1cs00239b}, url = {https://doi.org/10.1039/d1cs00239b} }- RIS
TY - JOUR AU - Wang, Chao AU - Chi, Weijie AU - Qiao, Qinglong AU - Tan, Davin AU - Xu, Zhaochao AU - Liu, Xiaogang TI - Twisted intramolecular charge transfer (TICT) and twists beyond TICT: from mechanisms to rational designs of bright and sensitive fluorophores JO - Chemical Society Reviews VL - 50 IS - 22 SP - 12656 EP - 12678 PY - 2021 DA - 2021/01/01 DO - 10.1039/d1cs00239b UR - https://doi.org/10.1039/d1cs00239b ER -
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