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Hang Zhou, Xianfeng Yi, Hui Yu, Liang Wang, Wei Chen, Yucai Qin, Ming Wang, Jia‐Bi Ma, Xuefeng Chu, Yeqing Wang and 8 more
Isolating and stabilizing boron Oxidative dehydrogenation of propane can produce propene from shale gas and help to replace petroleum as a propene feedstock. Boron-based catalysts can have high selectivity to propene, but the water by-product can deactivate the catalyst by hydrolyzing boron. Zhou et al. synthesized boron-doped silicate zeolites containing isolated boron sites that were stable against hydrolysis. The catalyst could achieve one-pass propane conversions up to ∼44% with selectivities for propene and >80% for ethene. They observed no deactivation after a 210-hour continuous test. Science , this issue p. 76
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Zhou, H., Yi, X., Yu, H., Wang, L., Chen, W., Qin, Y., Wang, M., Ma, J., Chu, X., Wang, Y., Hong, X., Chen, Z., Meng, X., Wang, H., Zhu, Q., Song, L., Zheng, A., & Xiao, F. (2021). Isolated boron in zeolite for oxidative dehydrogenation of propane. Science, 372(6537), 76–80. https://doi.org/10.1126/science.abe7935
Zhou, Hang, et al. "Isolated boron in zeolite for oxidative dehydrogenation of propane." Science, vol. 372, no. 6537, 2021, pp. 76–80, https://doi.org/10.1126/science.abe7935.
Zhou, Hang, Xianfeng Yi, Hui Yu, Liang Wang, Wei Chen, Yucai Qin, Ming Wang, et al. "Isolated boron in zeolite for oxidative dehydrogenation of propane." Science 372, no. 6537 (2021): 76–80. https://doi.org/10.1126/science.abe7935.
Zhou H., Yi X., Yu H. [и др.] Isolated boron in zeolite for oxidative dehydrogenation of propane // Science. — 2021. — Vol. 372, № 6537. — P. 76–80. — URL: https://doi.org/10.1126/science.abe7935
@article{zhou2021isolated,
title = {{Isolated boron in zeolite for oxidative dehydrogenation of propane}},
author = {Hang Zhou and Xianfeng Yi and Hui Yu and Liang Wang and Wei Chen and Yucai Qin and Ming Wang and Jia‐Bi Ma and Xuefeng Chu and Yeqing Wang and Xin Hong and Zifeng Chen and Xiangju Meng and Hai Wang and Qiuyan Zhu and Lijuan Song and Anmin Zheng and Feng‐Shou Xiao},
journal = {Science},
year = {2021},
volume = {372},
number = {6537},
pages = {76--80},
doi = {10.1126/science.abe7935},
url = {https://doi.org/10.1126/science.abe7935}
}TY - JOUR AU - Zhou, Hang AU - Yi, Xianfeng AU - Yu, Hui AU - Wang, Liang AU - Chen, Wei AU - Qin, Yucai AU - Wang, Ming AU - Ma, Jia‐Bi AU - Chu, Xuefeng AU - Wang, Yeqing AU - Hong, Xin AU - Chen, Zifeng AU - Meng, Xiangju AU - Wang, Hai AU - Zhu, Qiuyan AU - Song, Lijuan AU - Zheng, Anmin AU - Xiao, Feng‐Shou TI - Isolated boron in zeolite for oxidative dehydrogenation of propane JO - Science VL - 372 IS - 6537 SP - 76 EP - 80 PY - 2021 DA - 2021/04/01 DO - 10.1126/science.abe7935 UR - https://doi.org/10.1126/science.abe7935 ER -
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